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A Method of In-Situ Polymerization Functionalization of Nanotubes for Composite Applications

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Tech ID:
08-096
Principal Investigator:
Dr. Wang and Dr. Liang
Licensing Manager:
Description:

This invention provides a novel technique to enhance carbon nanotube dispersion and interfacial bonding in epoxy-based nanotube nanocomposites through in-situ polymerization. The in-situ polymerization reaction grafts peroxide groups onto the surfaces of nanotubes and the functionalized carbon nanotubes or nanofibers react with epoxy resin during nanocomposites fabrication. This in-situ polymerization can lead to high-exfoliation and uniform dispersion of carbon nanotubes or nanofibers in the epoxy polymer matrix during modification of nanotube surface characters. Furthermore the in-situ reaction produces covalent bond between nanotubes or nanofibers and the epoxy polymer matrix during composite fabrication through drafted peroxide groups to substantially improve load-transfer between nanotubes and resin. The significantly improved dispersion and interface bonding considerably increase the load-transfer and acquire high performance.

Applications:

  • This invention has excellent potential for use in the mass production of high-performance nanotube and nanofiber reinforced epoxy composites for multifunctional applications, such as lightweight high-performance structural materials, electromagnetic interference, and thermal management materials, etc.
  • Immediate applications include composite applications for aircraft, thermal management for electronic device package, etc. The yield rate using this method is almost I 00% and has the excellent potential for low cost mass production and scale-up.